Crystal structure and physical properties of a dithiolene complex crystal with adamantane supramolecular rotator


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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/56607

Title:	Crystal structure and physical properties of a dithiolene complex crystal with adamantane supramolecular rotator
Authors:	Yan, Yin-Nan Browse this author
	Kubo, Kazuya Browse this author →KAKEN DB
	Noro, Shin-ichiro Browse this author →KAKEN DB
	Akutagawa, Tomoyuki Browse this author →KAKEN DB
	Nakamura, Takayoshi Browse this author →KAKEN DB
Issue Date:	Mar-2014
Publisher:	日本化学会
Journal Title:	Bulletin of The Chemical Society of Japan
Volume:	87
Issue:	3
Start Page:	417
End Page:	419
Publisher DOI:	10.1246/bcsj.20130316
Abstract:	Supramolecular cation salt of adamantane rotator with a dithiolene complex, (fluoroadamantylammonium(+))([18]-crown-6)[Ni(dmit)(2)](-) (1) was synthesized. The fluorine atom of the adamantane unit showed a large thermal factor elongated latitudinally, suggesting molecular rotation in the solid state. Crystal 1 exhibited a large dielectric response by applying an AC field along the a axis.
Type:	article (author version)
URI:	http://hdl.handle.net/2115/56607
Appears in Collections:	電子科学研究所 (Research Institute for Electronic Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 久保和也

OAI-PMH ( junii2 , jpcoar_1.0 )

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