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Crystal structure and physical properties of a dithiolene complex crystal with adamantane supramolecular rotator

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Title: Crystal structure and physical properties of a dithiolene complex crystal with adamantane supramolecular rotator
Authors: Yan, Yin-Nan Browse this author
Kubo, Kazuya Browse this author →KAKEN DB
Noro, Shin-ichiro Browse this author →KAKEN DB
Akutagawa, Tomoyuki Browse this author →KAKEN DB
Nakamura, Takayoshi Browse this author →KAKEN DB
Issue Date: Mar-2014
Publisher: 日本化学会
Journal Title: Bulletin of The Chemical Society of Japan
Volume: 87
Issue: 3
Start Page: 417
End Page: 419
Publisher DOI: 10.1246/bcsj.20130316
Abstract: Supramolecular cation salt of adamantane rotator with a dithiolene complex, (fluoroadamantylammonium(+))([18]-crown-6)[Ni(dmit)(2)](-) (1) was synthesized. The fluorine atom of the adamantane unit showed a large thermal factor elongated latitudinally, suggesting molecular rotation in the solid state. Crystal 1 exhibited a large dielectric response by applying an AC field along the a axis.
Type: article (author version)
URI: http://hdl.handle.net/2115/56607
Appears in Collections:電子科学研究所 (Research Institute for Electronic Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 久保 和也

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