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Influence of post-treatment operations on structural properties and photocatalytic activity of octahedral anatase titania particles prepared by an ultrasonication-hydrothermal reaction

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タイトル: Influence of post-treatment operations on structural properties and photocatalytic activity of octahedral anatase titania particles prepared by an ultrasonication-hydrothermal reaction
著者: Wei, Zhishun 著作を一覧する
Kowalska, Ewa 著作を一覧する
Ohtani, Bunsho 著作を一覧する
キーワード: titania
photocatalytic activity
octahedral anatase particles
post-treatments
time-resolved microwave conductivity
発行日: 2014年12月
出版者: MDPI
誌名: Molecules
巻: 19
号: 12
開始ページ: 19573
終了ページ: 19587
出版社 DOI: 10.3390/molecules191219573
抄録: The influence of changes in structural and physical properties on the photocatalytic activity of octahedral anatase particles (OAPs), exposing eight equivalent {101} facets, caused by calcination (2 h) in air or grinding (1 h) in an agate mortar was studied with samples prepared by ultrasonication (US; 1 h)-hydrothermal reaction (HT; 24 h, 433 K). Calcination in air at temperatures up to 1173 K induced particle shape changes, evaluated by aspect ratio (AR; d(001)/d(101) = depth vertical to anatase {001} and {101} facets estimated by the Scherrer equation with data obtained from X-ray diffraction (XRD) patterns) and content of OAP and semi-OAP particles, without transformation into rutile. AR and OAP content, as well as specific surface area (SSA), were almost unchanged by calcination at temperatures up to 673 K and were then decreased by elevating the calcination temperature, suggesting that calcination at a higher temperature caused dull-edging and particle sintering, the latter also being supported by the analysis of particle size using XRD patterns and scanning electron microscopic (SEM) images. Time-resolved microwave conductivity (TRMC) showed that the maximum signal intensity (I-max), corresponding to a product of charge-carrier density and mobility, and signal-decay rate, presumably corresponding to reactivity of charge carriers, were increased with increase in AR, suggesting higher photocatalytic activity of OAPs than that of dull-edged particles. Grinding also decreased the AR, indicating the formation of dull-edged particles. The original non-treated samples showed activities in the oxidative decomposition of acetic acid (CO2 system) and dehydrogenation of methanol (H-2 system) comparable to and lower than those of a commercial anatase titania (Showa Denko Ceramics FP-6), respectively. The activities of calcined and ground samples for the CO2 system and H-2 system showed almost linear relations with AR and I-max, respectively, suggesting that those activities may depend on different properties.
資料タイプ: article
URI: http://hdl.handle.net/2115/58024
出現コレクション:雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

提供者: Ewa Kowalska

 

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