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Quantitative evaluation of ball-milling effects on the hydrolysis of cellulose catalysed by activated carbon

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Title: Quantitative evaluation of ball-milling effects on the hydrolysis of cellulose catalysed by activated carbon
Authors: Yabushita, Mizuho Browse this author
Kobayashi, Hirokazu Browse this author →KAKEN DB
Hara, Kenji Browse this author →KAKEN DB
Fukuoka, Atsushi Browse this author →KAKEN DB
Issue Date: 13-Mar-2014
Publisher: Royal Society of Chemistry
Journal Title: Catalysis science & technology
Volume: 4
Issue: 8
Start Page: 2312
End Page: 2317
Publisher DOI: 10.1039/c4cy00175c
Abstract: The synthesis of glucose from cellulose is a critical roadblock for establishing a new sustainable cycle of biorefinery to produce bio-based and environmentally-benign chemicals. We have previously demonstrated that the pre-treatment ball-milling of solid cellulose and a solid catalyst ( mix-milling) drastically improves the yield of glucose and oligosaccharides; however, the effect of this type of ball-milling has not been quantitatively evaluated. In this study, we performed several model reactions and found that the mix-milling method drastically enhanced the solid-solid reactions, such as the hydrolysis of insoluble cellulose to soluble oligomers on the solid catalyst, but not liquid-solid reactions. The kinetic study indicated that the rate constant of hydrolysis of cellulose to oligomers using mix-milling was 13-fold higher than that using individual milling. Owing to the fast depolymerisation of cellulose, we achieved a 72% yield of glucose with 97% conversion of cellulose and 74% selectivity at 418 K.
Rights: http://creativecommons.org/licenses/by/3.0/
Type: article
URI: http://hdl.handle.net/2115/58050
Appears in Collections:触媒科学研究所 (Institute for Catalysis) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 福岡 淳

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