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Ring-opening polymerization of a 2,3-disubstituted oxirane leading to a polyether having a carbonyl-aromatic pi-stacked structure

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Title: Ring-opening polymerization of a 2,3-disubstituted oxirane leading to a polyether having a carbonyl-aromatic pi-stacked structure
Authors: Merlani, Maia Browse this author
Koyama, Yasuhito Browse this author →KAKEN DB
Sato, Hiroyasu Browse this author
Geng, Li Browse this author
Barbakadze, Vakhtang Browse this author
Chankvetadze, Bezhan Browse this author
Nakano, Tamaki Browse this author →KAKEN DB
Issue Date: 16-Jan-2015
Publisher: Royal Soc Chemistry
Journal Title: Polymer Chemistry
Volume: 6
Issue: 11
Start Page: 1932
End Page: 1936
Publisher DOI: 10.1039/c4py01711k
Abstract: 2-Methoxycarbonyl-3-(3,4-dimethoxyphenyl) oxirane was synthesized and polymerized using a cationic initiator to afford a polymer having a rather stiff, stretched conformation. The side-chain methoxycarbonyl group and 3,4-dimethoxyphenyl group of neighboring monomeric units may form a hetero pi-stacked structure between side-chain carbonyl and aromatic groups which leads to intramolecular charge transfer (ICT) interactions. 2-Ethoxy-carbonyl- 3-phenyloxirane failed in polymerization, leading only to small molecules including cyclic compounds.
Rights: © The Royal Society of Chemistry 2015
Type: article (author version)
URI: http://hdl.handle.net/2115/60474
Appears in Collections:触媒科学研究所 (Institute for Catalysis) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 中野 環

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