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Ring-opening polymerization of a 2,3-disubstituted oxirane leading to a polyether having a carbonyl-aromatic pi-stacked structure
| Title: | Ring-opening polymerization of a 2,3-disubstituted oxirane leading to a polyether having a carbonyl-aromatic pi-stacked structure |
| Authors: | Merlani, Maia Browse this author | | Koyama, Yasuhito Browse this author →KAKEN DB | | Sato, Hiroyasu Browse this author | | Geng, Li Browse this author | | Barbakadze, Vakhtang Browse this author | | Chankvetadze, Bezhan Browse this author | | Nakano, Tamaki Browse this author →KAKEN DB |
| Issue Date: | 16-Jan-2015 |
| Publisher: | Royal Soc Chemistry |
| Journal Title: | Polymer Chemistry |
| Volume: | 6 |
| Issue: | 11 |
| Start Page: | 1932 |
| End Page: | 1936 |
| Publisher DOI: | 10.1039/c4py01711k |
| Abstract: | 2-Methoxycarbonyl-3-(3,4-dimethoxyphenyl) oxirane was synthesized and polymerized using a cationic initiator to afford a polymer having a rather stiff, stretched conformation. The side-chain methoxycarbonyl group and 3,4-dimethoxyphenyl group of neighboring monomeric units may form a hetero pi-stacked structure between side-chain carbonyl and aromatic groups which leads to intramolecular charge transfer (ICT) interactions. 2-Ethoxy-carbonyl- 3-phenyloxirane failed in polymerization, leading only to small molecules including cyclic compounds. |
| Rights: | © The Royal Society of Chemistry 2015 |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/60474 |
| Appears in Collections: | 触媒科学研究所 (Institute for Catalysis) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 中野 環
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