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Deprotonation of a dinuclear copper complex of 3,5-diamino-1,2,4-triazole for high oxygen reduction activity

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Title: Deprotonation of a dinuclear copper complex of 3,5-diamino-1,2,4-triazole for high oxygen reduction activity
Authors: Kato, Masaru Browse this author →KAKEN DB
Kimijima, Ken'ichi Browse this author
Shibata, Mari Browse this author
Notsu, Hideo Browse this author
Ogino, Kazuya Browse this author
Inokuma, Kiyoshi Browse this author
Ohta, Narumi Browse this author
Uehara, Hiromitsu Browse this author
Uemura, Yohei Browse this author
Oyaizu, Nobuhisa Browse this author
Ohba, Tadashi Browse this author
Takakusagi, Satoru Browse this author
Asakura, Kiyotaka Browse this author
Yagi, Ichizo Browse this author →KAKEN DB
Issue Date: 3-Mar-2015
Publisher: The Royal Society of Chemistry
Journal Title: Physical chemistry chemical physics
Volume: 17
Issue: 14
Start Page: 8638
End Page: 8641
Publisher DOI: 10.1039/c4cp05595k
PMID: 25759865
Abstract: A dinuclear copper(II) complex of 3,5-diamino-1,2,4-triazole is one of the highly active copper-based catalysts for the oxygen reduction reaction (ORR) in basic solutions. Our in situ X-ray absorption near edge structure measurements revealed that deprotonation of the triazole ligand might cause coordination geometrical changes, resulting in the enhancement of the ORR activity.
Type: article (author version)
URI: http://hdl.handle.net/2115/60824
Appears in Collections:環境科学院・地球環境科学研究院 (Graduate School of Environmental Science / Faculty of Environmental Earth Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 八木 一三

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