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An Investigation of Ni2P Single Crystal Surfaces : Structure, Electronic State and Reactivity

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Title: An Investigation of Ni2P Single Crystal Surfaces : Structure, Electronic State and Reactivity
Authors: Yuan, Qiuyi Browse this author
Ariga, Hiroko Browse this author →KAKEN DB
Asakura, Kiyotaka Browse this author →KAKEN DB
Keywords: Single crystal surfaces
Nickel phosphide
Electronic structure
Surface structure
Scanning tunneling microscopy
Density functional theory
LEED IV
Issue Date: Apr-2015
Publisher: Springer
Journal Title: Topics in catalysis
Volume: 58
Issue: 4-6
Start Page: 194
End Page: 200
Publisher DOI: 10.1007/s11244-015-0360-6
Abstract: Ni2P has demonstrated high catalytic activity for hydrodesulfurization and has recently been employed as a catalyst in a variety of other reactions. We have thoroughly reviewed the literature concerning Ni2P single crystal surfaces, with the aim of determining the relationship between surface structure and catalytic properties. Published results to date indicate that Ni2P single crystal surfaces exhibit reconstructed structures, and so the bulk terminated structure may not be stable. We have also reviewed the surface structures and electronic states of (1 x 1) and reconstructed Ni2P(0001) and (1010). Based on these reviews, this paper presents general rules regarding stabilization of the Ni2P surface structure and discusses the role of phosphorus in the single crystal surfaces.
Rights: The final publication is available at link.springer.com
Type: article (author version)
URI: http://hdl.handle.net/2115/61040
Appears in Collections:触媒科学研究所 (Institute for Catalysis) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 朝倉 清高

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