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Dehydration of sorbitol to isosorbide over H-beta zeolites with high Si/Al ratios

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Title: Dehydration of sorbitol to isosorbide over H-beta zeolites with high Si/Al ratios
Authors: Kobayashi, Hirokazu Browse this author →KAKEN DB
Yokoyama, Haruka Browse this author
Feng, Bo Browse this author
Fukuoka, Atsushi Browse this author →KAKEN DB
Issue Date: May-2015
Publisher: The Royal Society of Chemistry
Journal Title: Green chemistry
Volume: 17
Issue: 5
Start Page: 2732
End Page: 2735
Publisher DOI: 10.1039/c5gc00319a
Abstract: Conversion of sorbitol to isosorbide by heterogeneous catalysts is a challenge in biorefinery. Herein, H-beta zeolites with specific Si/Al ratios uniquely give isosorbide in up to 76% yield under mild conditions. Mechanistic study has suggested that acid sites on hydrophobic internal surface are active for this reaction.
Type: article (author version)
URI: http://hdl.handle.net/2115/61446
Appears in Collections:触媒科学研究所 (Institute for Catalysis) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 福岡 淳

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