Cluster-pi electronic interaction in a superatomic Au-13 cluster bearing sigma-bonded acetylide ligands


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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/62372

Title:	Cluster-pi electronic interaction in a superatomic Au-13 cluster bearing sigma-bonded acetylide ligands
Authors:	Sugiuchi, Mizuho Browse this author
	Shichibu, Yukatsu Browse this author →KAKEN DB
	Nakanishi, Takayuki Browse this author →KAKEN DB
	Konishi, Katsuaki Browse this author →KAKEN DB
	Hasegawa, Yasuchika Browse this author →KAKEN DB
Issue Date:	8-Jul-2016
Publisher:	Royal Society of Chemistry
Journal Title:	Chemical communications
Volume:	51
Issue:	70
Start Page:	13519
End Page:	13522
Publisher DOI:	10.1039/c5cc04312c
PMID:	26215256
Abstract:	An organometallic Au-13 cluster having two sigma-bonded acetylide ligands was synthesized and its structure was determined by X-ray crystallography. Absorption spectral studies indicated the presence of electronic coupling between the superatomic Au-13 core and the acetylide pi-orbitals, which was supported by theoretical considerations.
Type:	article (author version)
URI:	http://hdl.handle.net/2115/62372
Appears in Collections:	環境科学院・地球環境科学研究院 (Graduate School of Environmental Science / Faculty of Environmental Earth Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 小西克明

OAI-PMH ( junii2 , jpcoar_1.0 )

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