HUSCAP logo Hokkaido Univ. logo

Hokkaido University Collection of Scholarly and Academic Papers >
Institute for Catalysis >
Peer-reviewed Journal Articles, etc >

Exploring the catalytic properties of supported palladium catalysts in the transfer hydrogenolysis of glycerol

This item is licensed under: Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International

Files in This Item:
CTH glycerol_manuscript_MauAsa.pdf3.51 MBPDFView/Open
Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/63548

Title: Exploring the catalytic properties of supported palladium catalysts in the transfer hydrogenolysis of glycerol
Authors: Mauriello, F. Browse this author
Ariga, H. Browse this author →KAKEN DB
Musolino, M.G. Browse this author
Pietropaolo, R. Browse this author
Takakusagi, S. Browse this author →KAKEN DB
Asakura, K. Browse this author →KAKEN DB
Keywords: Catalytic transfer hydrogenolysis (CTH)
Glycerol valorization
1,2-Propanediol
Coprecipitated palladium catalysts
Strong metal support interaction
Issue Date: May-2015
Publisher: Elsevier
Journal Title: Applied catalysis B : environmental
Volume: 166
Start Page: 121
End Page: 131
Publisher DOI: 10.1016/j.apcatb.2014.11.014
Abstract: The transfer hydrogenolysis of glycerol promoted by supported palladium catalysts is reported. The reactions were carried out under mild conditions (453K and 5 bar of N-2) in absence of added hydrogen by using the reaction solvent, 2-propanol, as hydrogen source. The catalytic results are interpreted in terms of metal (Pd)-metal (Co or Fe) interaction that modifies the electronic properties of palladium and affords bimetallic PdM sites (M= Co or Fe), thus enhancing the catalytic properties of the systems in the conversion of glycerol as well as in the selectivity to 1,2-propanediol and 1-propanol. The transfer hydrogenolysis mechanism is here elucidated and involves the glycerol dehydration to 1-hydroxyacetone and the subsequent hydrogenation of 1-hydroxyacetone to propylene glycol.
Rights: (C) 2015 Elsevier B.V. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/.
http://creativecommons.org/licenses/by-nc-nd/4.0/
Type: article (author version)
URI: http://hdl.handle.net/2115/63548
Appears in Collections:触媒科学研究所 (Institute for Catalysis) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 朝倉 清高

Export metadata:

OAI-PMH ( junii2 , jpcoar )

MathJax is now OFF:


 

 - Hokkaido University