|
Hokkaido University Collection of Scholarly and Academic Papers >
Institute for Catalysis >
Peer-reviewed Journal Articles, etc >
Synthesis of poly(1,10-phenanthroline-5,6-diyl)s having a pi-stacked, helical conformation
| Title: | Synthesis of poly(1,10-phenanthroline-5,6-diyl)s having a pi-stacked, helical conformation |
| Authors: | Yang, Weixi Browse this author | | Nakano, Tamaki Browse this author →KAKEN DB |
| Issue Date: | 18-Dec-2015 |
| Publisher: | Royal Society of Chemistry |
| Journal Title: | Chemical Communications |
| Volume: | 51 |
| Issue: | 97 |
| Start Page: | 17269 |
| End Page: | 17272 |
| Publisher DOI: | 10.1039/c5cc07005h |
| PMID: | 26461471 |
| Abstract: | 5,6-Dibromo-1,10-phenanthroline and 2,9-di-n-butyl-5,6-dibromo-1,10-phenanthroline were polymerized using a Ni catalyst to afford helical polymers in which the phenanthroline moieties are densely stacked on top of each other. Polymerization of the latter monomer using a chiral catalyst led to a preferred-handed helix. This is the first Ni-catalyzed helix-sense-selective polymerization of aromatic compounds. |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/63829 |
| Appears in Collections: | 触媒科学研究所 (Institute for Catalysis) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
|
Submitter: 中野 環
|
