HUSCAP logo Hokkaido Univ. logo

Hokkaido University Collection of Scholarly and Academic Papers >
触媒科学研究所  >
雑誌発表論文等  >

TiO2-Supported Re as a General and Chemoselective Heterogeneous Catalyst for Hydrogenation of Carboxylic Acids to Alcohols

フルテキスト
Supporting Information_Chem Eur J_2017.pdfSupporting Information5.88 MBPDF見る/開く
Main text_Chem Eur J_2017.pdf640.39 kBPDF見る/開く
この文献へのリンクには次のURLを使用してください:http://hdl.handle.net/2115/67661

タイトル: TiO2-Supported Re as a General and Chemoselective Heterogeneous Catalyst for Hydrogenation of Carboxylic Acids to Alcohols
著者: Toyao, Takashi 著作を一覧する
Siddiki, S. M. A. Hakim 著作を一覧する
Touchy, Abeda S. 著作を一覧する
Onodera, Wataru 著作を一覧する
Kon, Kenichi 著作を一覧する
Morita, Yoshitsugu 著作を一覧する
Kamachi, Takashi 著作を一覧する
Yoshizawa, Kazunari 著作を一覧する
Shimizu, Ken-ichi 著作を一覧する
キーワード: alcohols
carboxylic acids
heterogeneous catalysis
hydrogenation
rhenium
発行日: 2017年 1月23日
出版者: Wiley-Blackwell
誌名: Chemistry-A European journal
巻: 23
号: 5
開始ページ: 1001
終了ページ: 1006
出版社 DOI: 10.1002/chem.201604762
抄録: TiO2-supported Re, Re/TiO2, was found to promote selective hydrogenation of carboxylic acids having aromatic and aliphatic moieties to the corresponding alcohols. Re/TiO2 showed superior results compared to other transition-metal-loaded TiO2 and supported Re catalysts for selective hydrogenation of 3-phenylpropionic acid. 3phenylpropanol was produced in 97% yield under mild conditions (5 MPa H-2 at 140 degrees C). Contrary to typical heterogeneous catalysts, Re/TiO2 does not lead to the formation of dearomatized byproducts. The catalyst is recyclable and shows a wide substrate scope in the synthesis of alcohols (22 examples; up to 97% isolated yield).
Rights: This is the peer reviewed version of the following article: Chemistry A European journal, 23(5), 2017-01-23, Pages 1001-1006, which has been published in final form at http://dx.doi.org/10.1002/chem.201604762. This article may be used for non-commercial purposes in accordance With Wiley-VCH Terms and Conditions for Self-archiving.
資料タイプ: article (author version)
URI: http://hdl.handle.net/2115/67661
出現コレクション:雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

提供者: 鳥屋尾 隆

 

本サイトに関するご意見・お問い合わせは repo at lib.hokudai.ac.jp へお願いします。 - 北海道大学