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Hokkaido University Collection of Scholarly and Academic Papers >
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Dehydrogenation of the NH−NH Bond Triggered by Potassium tert-Butoxide in Liquid Ammonia
| Title: | Dehydrogenation of the NH−NH Bond Triggered by Potassium tert-Butoxide in Liquid Ammonia |
| Authors: | Wang, Lei Browse this author | | Ishida, Akiko Browse this author | | Hashidoko, Yasuyuki Browse this author →KAKEN DB | | Hashimoto, Makoto Browse this author →KAKEN DB |
| Keywords: | trigger | | t-Butoxide |
| Issue Date: | 16-Jan-2017 |
| Publisher: | Wiley-VCH |
| Journal Title: | Angewandte Chemie International Edition |
| Volume: | 56 |
| Issue: | 3 |
| Start Page: | 870 |
| End Page: | 873 |
| Publisher DOI: | 10.1002/anie.201610371 |
| PMID: | 27936299 |
| Abstract: | A novel strategy for the dehydrogenation of NH-NH bond is disclosed using potassium t-butoxide (tBuOK) in liquid NH3 under air (O2) at room temperature. Its synthetic values are well demonstrated via highly efficient synthesis of aromatic azo compounds (up to 100% yield, 3 min), heterocyclic azo compounds, and dehydrazination of phenylhydrazine. The broad application of this strategy and its benefit to chemical biology is proved by a novel, convenient, one-pot and efficient synthesis of aliphatic diazirines, which are important photoreactive agents for photoaffinity labeling. |
| Rights: | This is the peer reviewed version of the following article: Angewandte chemie-international edition 56(3), pp870-873, 2017, which has been published in final form at http://dx.doi.org/10.1002/anie.201610371. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/68124 |
| Appears in Collections: | 農学院・農学研究院 (Graduate School of Agriculture / Faculty of Agriculture) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 橋本 誠
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