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Chiral bifunctional organocatalysts bearing a 1,3-propanediamine unit for the aza-MBH reaction
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| Title: | Chiral bifunctional organocatalysts bearing a 1,3-propanediamine unit for the aza-MBH reaction |
| Authors: | Hirata, Shuichi Browse this author | | Tanaka, Kouichi Browse this author | | Matsui, Katsuya Browse this author | | Arteaga, Fernando Arteaga Browse this author | | Yoshida, Yasushi Browse this author | | Takizawa, Shinobu Browse this author | | Sasai, Hiroaki Browse this author |
| Issue Date: | Oct-2013 |
| Publisher: | Elsevier |
| Journal Title: | Tetrahedron: Asymmetry |
| Volume: | 24 |
| Issue: | 19 |
| Start Page: | 1189 |
| End Page: | 1192 |
| Publisher DOI: | 10.1016/j.tetasy.2013.08.005 |
| Abstract: | The introduction of a 1,3-propanediamine unit at the 3-position of (S)-BINOL using a methylene spacer led to the formation of a chiral bifunctional organocatalyst for the aza-Morita-Baylis-Hillman (aza-MBH) reaction. The organocatalyst 1k mediated aza-MBH transformations with high chemical yields and with up to 82% ee. |
| Rights: | © 2018. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ | | http://creativecommons.org/licenses/by-nc-nd/4.0/ |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/72250 |
| Appears in Collections: | 高等教育推進機構 (Institute for the Advancement of Higher Education) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: Fernando Arteaga Arteaga
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