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P-chirogenic organocatalysts : application to the aza-Morita-Baylis-Hillman (aza-MBH) reaction of ketimines

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Title: P-chirogenic organocatalysts : application to the aza-Morita-Baylis-Hillman (aza-MBH) reaction of ketimines
Authors: Takizawa, Shinobu Browse this author
Rémond, Emmanuelle Browse this author
Arteaga, Fernando Arteaga Browse this author
Yoshida, Yasushi Browse this author
Sridharan, Vellaisamy Browse this author
Bayardon, Jérôme Browse this author
Jugé, Sylvain Browse this author
Sasai, Hiroaki Browse this author
Issue Date: 22-Jul-2013
Publisher: Royal Society of Chemistry
Journal Title: Chemical Communications
Volume: 49
Issue: 75
Start Page: 8392
End Page: 8394
Publisher DOI: 10.1039/c3cc44549f
Abstract: The P-chirogenic organocatalysts were found to promote the enantioselective aza-Morita–Baylis–Hillman reaction of ketimines derived from acyclic α-keto esters. In the P-chirogenic organocatalyzed aza-MBH reactions, α,α-disubstituted α-amino acid derivatives were obtained in high yields with high enantioselectivities (up to 97% ee).
Type: article (author version)
URI: http://hdl.handle.net/2115/72251
Appears in Collections:高等教育推進機構 (Institute for the Advancement of Higher Education) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: Fernando Arteaga Arteaga

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