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Acceptorless dehydrogenation of N-heterocycles by supported Pt catalysts

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Title: Acceptorless dehydrogenation of N-heterocycles by supported Pt catalysts
Authors: Moromi, Sondomoyee K. Browse this author
Siddiki, S. M. A. H. Browse this author
Kon, Kenichi Browse this author
Toyao, Takashi Browse this author →KAKEN DB
Shimizu, Ken-ichi Browse this author →KAKEN DB
Keywords: Pt nanoparticles
Dehydrogenation
N-heterocycles
Hydrogen storage
Issue Date: 1-Mar-2017
Publisher: Elsevier
Journal Title: Catalysis today
Volume: 281
Start Page: 507
End Page: 511
Publisher DOI: 10.1016/j.cattod.2016.06.027
Abstract: Pt metal nanoparticles loaded on various supports and carbon-supported various metal catalysts are tested for dehydrogenation of 6-methyl-1,2,3,4- tetrahydroquinoline to 6-methyl-quinoline under oxidant-free conditions. In the 20 types of the catalysts screened, carbon-supported Pt catalyst (Pt/C) shows the highest activity. Pt/C is reusable after the reaction and is effective for dehydrogenation of various N-heterocycles (tetrahydroquinolines and indoline). Pt/C is also effective for hydrogenation of quinoline under 3 bar H-2. The results demonstrate that this catalytic method may be useful for an organic hidride-based hydrogen storage system.
Rights: © 2016 Elsevier B.V. All rights reserved. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
http://creativecommons.org/licenses/by-nc-nd/4.0/
Type: article (author version)
URI: http://hdl.handle.net/2115/72825
Appears in Collections:触媒科学研究所 (Institute for Catalysis) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 清水 研一

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