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Acceptorless dehydrogenation of N-heterocycles by supported Pt catalysts
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Title: | Acceptorless dehydrogenation of N-heterocycles by supported Pt catalysts |
Authors: | Moromi, Sondomoyee K. Browse this author | Siddiki, S. M. A. H. Browse this author | Kon, Kenichi Browse this author | Toyao, Takashi Browse this author →KAKEN DB | Shimizu, Ken-ichi Browse this author →KAKEN DB |
Keywords: | Pt nanoparticles | Dehydrogenation | N-heterocycles | Hydrogen storage |
Issue Date: | 1-Mar-2017 |
Publisher: | Elsevier |
Journal Title: | Catalysis today |
Volume: | 281 |
Start Page: | 507 |
End Page: | 511 |
Publisher DOI: | 10.1016/j.cattod.2016.06.027 |
Abstract: | Pt metal nanoparticles loaded on various supports and carbon-supported various metal catalysts are tested for dehydrogenation of 6-methyl-1,2,3,4- tetrahydroquinoline to 6-methyl-quinoline under oxidant-free conditions. In the 20 types of the catalysts screened, carbon-supported Pt catalyst (Pt/C) shows the highest activity. Pt/C is reusable after the reaction and is effective for dehydrogenation of various N-heterocycles (tetrahydroquinolines and indoline). Pt/C is also effective for hydrogenation of quinoline under 3 bar H-2. The results demonstrate that this catalytic method may be useful for an organic hidride-based hydrogen storage system. |
Rights: | © 2016 Elsevier B.V. All rights reserved. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ | http://creativecommons.org/licenses/by-nc-nd/4.0/ |
Type: | article (author version) |
URI: | http://hdl.handle.net/2115/72825 |
Appears in Collections: | 触媒科学研究所 (Institute for Catalysis) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 清水 研一
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