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Stepwise topochemical fluorination of SrCrO3 perovskite via a super-structured oxide

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Title: Stepwise topochemical fluorination of SrCrO3 perovskite via a super-structured oxide
Authors: Su, Yu Browse this author
Tsujimoto, Yoshihiro Browse this author
Fujii, Kotaro Browse this author
Masubuchi, Yuji Browse this author →KAKEN DB
Ohata, Hirohito Browse this author
Iwai, Hideo Browse this author
Yashima, Masatomo Browse this author
Yamaura, Kazunari Browse this author →KAKEN DB
Issue Date: 25-Jun-2019
Publisher: Royal Society of Chemistry
Journal Title: Chemical communications
Volume: 55
Issue: 50
Start Page: 7239
End Page: 7242
Publisher DOI: 10.1039/c9cc02512j
Abstract: A topochemical reaction between SrCrO3 and polyvinylydene fluoride yields the new fluorinated phase SrCrO2.8F0.2. The transformation proceeds via a reduced oxide intermediate (SrCrO2.8) that can be isolated as a single phase by the reaction between SrCrO3 and g-C3N4. The fluoride ions randomly occupy anion sites despite an oxygen-vacancy ordered structure in SrCrO2.8.
Type: article (author version)
Appears in Collections:総合化学院 (Graduate School of Chemical Sciences and Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 辻本 吉廣

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