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Selective Transformations of Triglycerides into Fatty Amines, Amides, and Nitriles by using Heterogeneous Catalysis
Title: | Selective Transformations of Triglycerides into Fatty Amines, Amides, and Nitriles by using Heterogeneous Catalysis |
Authors: | Jamil, Md A. R. Browse this author | Siddiki, S. M. A. Hakim Browse this author | Touchy, Abeda Sultana Browse this author | Rashed, Md Nurnobi Browse this author | Poly, Sharmin Sultana Browse this author | Jing, Yuan Browse this author | Ting, Kah Wei Browse this author | Toyao, Takashi Browse this author →KAKEN DB | Maeno, Zen Browse this author →KAKEN DB | Shimizu, Ken-ichi Browse this author →KAKEN DB |
Keywords: | amidation | amination | biomass | heterogeneous catalysis | triglycerides |
Issue Date: | 5-Jul-2019 |
Publisher: | Wiley-Blackwell |
Journal Title: | ChemSusChem |
Volume: | 12 |
Issue: | 13 |
Start Page: | 3115 |
End Page: | 3125 |
Publisher DOI: | 10.1002/cssc.201900365 |
Abstract: | The use of triglycerides as an important class of biomass is an effective strategy to realize a more sustainable society. Herein, three heterogeneous catalytic methods are reported for the selective one-pot transformation of triglycerides into value-added chemicals: i) the reductive amination of triglycerides into fatty amines with aqueous NH3 under H-2 promoted by ZrO2-supported Pt clusters; ii) the amidation of triglycerides under gaseous NH3 catalyzed by high-silica H-beta (H beta) zeolite at 180 degrees C; iii) the H beta-promoted synthesis of nitriles from triglycerides and gaseous NH3 at 220 degrees C. These methods are widely applicable to the transformation of various triglycerides (C-4-C-18 skeletons) into the corresponding amines, amides, and nitriles. |
Rights: | This is the peer reviewed version of the following article: Md. A. R. Jamil Dr. S. M. A. Hakim Siddiki Dr. Abeda Sultana Touchy Md. Nurnobi Rashed Sharmin Sultana Poly Yuan Jing Kah Wei Ting Dr. Takashi Toyao Dr. Zen Maeno Prof. Dr. Ken-ichi Shimizu, Selective Transformations of Triglycerides into Fatty Amines, Amides, and Nitriles by using Heterogeneous Catalysis, ChemSusChem 2019, 12, 3115, which has been published in final form at https://doi.org/10.1002/cssc.201900365 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. |
Type: | article (author version) |
URI: | http://hdl.handle.net/2115/78814 |
Appears in Collections: | 触媒科学研究所 (Institute for Catalysis) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 清水 研一
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