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Synthesis of a Fluorescent Solvatochromic Resin Using Suzuki-Miyaura Cross-Coupling and Its Optical Waveguide Spectra to Measure the Solvent Polarity on the Surface

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Title: Synthesis of a Fluorescent Solvatochromic Resin Using Suzuki-Miyaura Cross-Coupling and Its Optical Waveguide Spectra to Measure the Solvent Polarity on the Surface
Authors: Otsuka, Yu Browse this author
Li, Guanglei Browse this author
Takahashi, Hiromi Browse this author
Satoh, Hisashi Browse this author →KAKEN DB
Yamada, Koji Browse this author →KAKEN DB
Keywords: Suzuki–Miyaura cross-coupling
solid-phase synthesis
optical waveguide spectrometry
Issue Date: Oct-2020
Publisher: MDPI
Journal Title: Materials
Volume: 13
Issue: 20
Start Page: 4483
Publisher DOI: 10.3390/ma13204483
Abstract: We have established a novel analytical method for solvent polarity on resin surface by combining the synthesis of fluorescent solvatochromic resin with optical waveguide spectrometry. The fluorescent solvatochromic resin was obtained via Suzuki-Miyaura cross-coupling between 4-iodobenzoic acid immobilized on Wang resin and 5-[4-(N,N-dihexylamino)phenyl]-2-thienylboronic acid N-methyl-iminodiacetic acid (MIDA) ester. The optical waveguide spectrometry studies on the resin showed a strong fluorescent solvatochromism in various organic solvents.
Rights: http://creativecommons.org/licenses/by/4.0/
Type: article
URI: http://hdl.handle.net/2115/80110
Appears in Collections:環境科学院・地球環境科学研究院 (Graduate School of Environmental Science / Faculty of Environmental Earth Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

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