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Ceria-supported palladium as a highly active and selective catalyst for oxidative decomposition of ammonium ion in water with ozone
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Title: | Ceria-supported palladium as a highly active and selective catalyst for oxidative decomposition of ammonium ion in water with ozone |
Authors: | Krisbiantoro, Philip Anggo Browse this author | Togawa, Tomokazu Browse this author | Kato, Koki Browse this author | Zhang, Jieqiong Browse this author | Otomo, Ryoichi Browse this author →KAKEN DB | Kamiya, Yuichi Browse this author →KAKEN DB |
Keywords: | Ozonation | Ammonia nitrogen | Palladium | Ceria | Wastewater treatment |
Issue Date: | 15-Jan-2021 |
Publisher: | Elsevier |
Journal Title: | Catalysis communications |
Volume: | 149 |
Start Page: | 106204 |
Publisher DOI: | 10.1016/j.catcom.2020.106204 |
Abstract: | Al2O3-supported precious metal catalysts were tested for the oxidative decomposition of NH4+ in water with O3 and the effects of support on the catalytic activity of Pd were investigated. Pd/CeO2 was found to be the best catalyst in terms of activity, selectivity and stability and was more active and selective than Co3O4, which is one of the best catalysts reported so far. The reaction proceeded only in the presence of Cl−. The moderate value of the d-band center relative to the Fermi level of Pd was found to be favorable for the activation of reactants, leading to a high catalytic performance. |
Rights: | © 2021. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ | https://creativecommons.org/licenses/by-nc-nd/4.0/ |
Type: | article |
URI: | http://hdl.handle.net/2115/80422 |
Appears in Collections: | 環境科学院・地球環境科学研究院 (Graduate School of Environmental Science / Faculty of Environmental Earth Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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