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Ceria-supported palladium as a highly active and selective catalyst for oxidative decomposition of ammonium ion in water with ozone

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Title: Ceria-supported palladium as a highly active and selective catalyst for oxidative decomposition of ammonium ion in water with ozone
Authors: Krisbiantoro, Philip Anggo Browse this author
Togawa, Tomokazu Browse this author
Kato, Koki Browse this author
Zhang, Jieqiong Browse this author
Otomo, Ryoichi Browse this author →KAKEN DB
Kamiya, Yuichi Browse this author →KAKEN DB
Keywords: Ozonation
Ammonia nitrogen
Palladium
Ceria
Wastewater treatment
Issue Date: 15-Jan-2021
Publisher: Elsevier
Journal Title: Catalysis communications
Volume: 149
Start Page: 106204
Publisher DOI: 10.1016/j.catcom.2020.106204
Abstract: Al2O3-supported precious metal catalysts were tested for the oxidative decomposition of NH4+ in water with O3 and the effects of support on the catalytic activity of Pd were investigated. Pd/CeO2 was found to be the best catalyst in terms of activity, selectivity and stability and was more active and selective than Co3O4, which is one of the best catalysts reported so far. The reaction proceeded only in the presence of Cl−. The moderate value of the d-band center relative to the Fermi level of Pd was found to be favorable for the activation of reactants, leading to a high catalytic performance.
Rights: © 2021. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
https://creativecommons.org/licenses/by-nc-nd/4.0/
Type: article
URI: http://hdl.handle.net/2115/80422
Appears in Collections:環境科学院・地球環境科学研究院 (Graduate School of Environmental Science / Faculty of Environmental Earth Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

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