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SrFe1-xSnxO3-delta nanoparticles with enhanced redox properties for catalytic combustion of benzene

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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/82687

Title: SrFe1-xSnxO3-delta nanoparticles with enhanced redox properties for catalytic combustion of benzene
Authors: Hashimoto, Kazutaka Browse this author
Otomo, Ryoichi Browse this author →KAKEN DB
Kamiya, Yuichi Browse this author →KAKEN DB
Issue Date: 21-Sep-2020
Publisher: Royal Society of Chemistry
Journal Title: Catalysis Science and Technology
Volume: 10
Issue: 18
Start Page: 6342
End Page: 6349
Publisher DOI: 10.1039/d0cy01154a
Abstract: A series of Sn-substituted strontium ferrates SrFe1-xSnxO3-delta (x = 0, 0.25, 0.50, 0.75 and 1.0) were prepared by the polymerized complex method. The influence of the substitution of Fe in SrFeO3-delta with Sn on structural, redox, and catalytic properties was investigated. X-ray diffraction and Fe-57 Mossbauer analyses revealed that the partial substitution of Fe with Sn expanded the lattice of the perovskite-type structure, leading to elongation of Fe-O bonds. The partial substitution resulted in the decline of the particle size and the increase of the specific surface area. H-2-TPR and TG measurements in a H-2 or O-2 flow indicated that the partial substitution significantly accelerated the redox rates of Fe at 500 degrees C. Due to the increased surface area and enhanced redox properties, the partially substituted SrFe1-xSnxO3-delta showed higher catalytic activity than SrFeO3-delta for the combustion of benzene.
Type: article (author version)
URI: http://hdl.handle.net/2115/82687
Appears in Collections:環境科学院・地球環境科学研究院 (Graduate School of Environmental Science / Faculty of Environmental Earth Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 大友 亮一

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