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Catalytic Methylation of Benzene over Pt/MoOx/TiO2 and Zeolite Catalyst Using CO2 and H-2
| Title: | Catalytic Methylation of Benzene over Pt/MoOx/TiO2 and Zeolite Catalyst Using CO2 and H-2 |
| Authors: | Ting, Kah Wei Browse this author | | Imbe, Takuto Browse this author | | Kamakura, Haruka Browse this author | | Maeno, Zen Browse this author →KAKEN DB | | Siddiki, S. M. A. Hakim Browse this author | | Matsushita, Koichi Browse this author | | Shimizu, Ken-ichi Browse this author →KAKEN DB | | Toyao, Takashi Browse this author →KAKEN DB |
| Keywords: | CO2 hydrogenation | | C-methylation | | One-pot synthesis |
| Issue Date: | Feb-2022 |
| Publisher: | 日本化学会（Chemical Society of Japan） |
| Journal Title: | Chemistry letters |
| Volume: | 51 |
| Issue: | 2 |
| Start Page: | 149 |
| End Page: | 152 |
| Publisher DOI: | 10.1246/cl.210664 |
| Abstract: | Catalytic methylation of benzene using CO2/H-2 was investigated using various combinations of supported metal catalysts and zeolites in a batch reactor. After a thorough catalyst screening process, the combination of Pt(3)/MoOx(30)/TiO2 and H-MOR (SiO2/Al2O3 = 90) was the most efficient, achieving up to 39% benzene-based yield and 27% CO2-based yield, without promoting the dearomatization of benzene, under the reaction conditions employed in this study (1 MPa CO2, 5 MPa H-2, 1 mmol of benzene, 240 degrees C, 12 h). |
| Type: | article |
| URI: | http://hdl.handle.net/2115/85149 |
| Appears in Collections: | 触媒科学研究所 (Institute for Catalysis) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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