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Protection Strategies for the Conversion of Biobased Furanics to Chemical Building Blocks

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Title: Protection Strategies for the Conversion of Biobased Furanics to Chemical Building Blocks
Authors: Coumans, Ferdy J. A. G. Browse this author
Overchenko, Zhanna Browse this author
Wiesfeld, Jan J. Browse this author
Kosinov, Nikolay Browse this author
Nakajima, Kiyotaka Browse this author →KAKEN DB
Hensen, Emiel J. M. Browse this author
Keywords: Biomass
Chemical building blocks
Side reactions
Issue Date: 2022
Publisher: American Chemical Society
Journal Title: sustainable chemistry & engineering
Volume: 10
Issue: 10
Start Page: 3116
End Page: 3130
Publisher DOI: 10.1021/acssuschemeng.1c06723
Abstract: In recent years, the urgency to replace fossil-based resources by renewablebiomass for obtaining chemical building blocks has only increased. Carbohydrate-derivedfuranic compounds are regarded as promising platforms for a renewable value chain. Thehigh reactivity of such biobased intermediates requires the development of novel catalyticchemistry to enhance product yield. The protection of reactive functional groupsprovides a way to improve the product selectivity. Such protection strategies are commonpractice in the synthesis offine chemicals and pharmaceuticals but are not fully exploredfor the conversion of furanic compounds. In this perspective, several examples ofprotection strategies focusing on the selective passivation of 5-HMF are discussed.Formation and removal of these protection groups are highlighted as well as theapplication of the neutralized 5-HMF in further processing. A guide for selecting theappropriate protection strategy depending on the targeted chemistry and operatingconditions is provided.
Type: article
Appears in Collections:触媒科学研究所 (Institute for Catalysis) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

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