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Surfactant induced bilayer-micelle transition for emergence of functions in anisotropic hydrogel
Title: | Surfactant induced bilayer-micelle transition for emergence of functions in anisotropic hydrogel |
Authors: | Haque, Md Anamul Browse this author | Kurokawa, Takayuki Browse this author →KAKEN DB | Nakajima, Tasuku Browse this author →KAKEN DB | Kamita, Gen Browse this author | Gong, Jian Ping Browse this author →KAKEN DB | Fatema, Zannatul Browse this author |
Issue Date: | 2022 |
Publisher: | Royal Society of Chemistry (RSC) |
Journal Title: | Journal of materials chemistry. B, Materials for biology and medicine |
Volume: | 10 |
Issue: | 41 |
Start Page: | 8386 |
End Page: | 8397 |
Publisher DOI: | 10.1039/D2TB00172A |
Abstract: | Tuning the self-assembled structures in amorphous hydrogels will enrich the functionality of hydrogels. In this study, we tuned the structure of a photonic hydrogel, which consists of polymeric lamellar bilayers entrapped inside a polyacrylamide network, simply by molecular triggering using an ionic surfactant. Owing to the binding of ionic surfactants (sodium dodecyl sulfate), the lamellar bilayers comprising of non-ionic polymeric surfactants [poly(dodecyl glyceryl itaconate)] changed to micelles, whereas the unidirectional lamellar structure was preserved in the hydrogel. The bilayer-micelle structure transition caused a dramatic decrease in the swelling anisotropy and mechanical softening of the photonic gel. With the micelle structure, the softened gel shows fast (0.3 s) and reversible color change over the entire visible light range in response to a small mechanical pressure (5 kPa). This low stress-induced color-changing hydrogel could be applied as a visual tactile sensor in various fields, especially in biomedical engineering. |
Type: | article (author version) |
URI: | http://hdl.handle.net/2115/90647 |
Appears in Collections: | 生命科学院・先端生命科学研究院 (Graduate School of Life Science / Faculty of Advanced Life Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 龔 剣萍 (Gong Jian Ping)
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