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Intercalation on Transition Metal Trichalcogenides via a Quasi-Amorphous Phase with 1D Order
| Title: | Intercalation on Transition Metal Trichalcogenides via a Quasi-Amorphous Phase with 1D Order |
| Authors: | Fujioka, Masaya Browse this author | | Jeem, Melbert Browse this author →KAKEN DB | | Sato, Kento Browse this author | | Tanaka, Masashi Browse this author | | Morita, Kazuki Browse this author | | Shibuya, Taizo Browse this author | | Takahashi, Kiyonori Browse this author →KAKEN DB | | Iwasaki, Suguru Browse this author →KAKEN DB | | Miura, Akira Browse this author | | Nagao, Masanori Browse this author →KAKEN DB | | Demura, Satoshi Browse this author | | Sakata, Hideaki Browse this author | | Ono, Madoka Browse this author →KAKEN DB | | Kaiju, Hideo Browse this author | | Nishii, Junji Browse this author →KAKEN DB |
| Keywords: | 1D materials | | intercalation | | quasi-amorphous phases | | superconductivity | | transition metal trichalcogenides |
| Issue Date: | 2-Mar-2023 |
| Publisher: | Wiley-Blackwell |
| Journal Title: | Advanced Functional Materials |
| Volume: | 33 |
| Issue: | 10 |
| Start Page: | 2208702 |
| Publisher DOI: | 10.1002/adfm.202208702 |
| Abstract: | Intercalation into 1D transition metal trichalcogenides (TMTs) in which fibers are bonded by a weak van der Waals force can be expected to create various intercalation compounds and develop unique physical properties according to the combination of the host materials and guest ions. However, structural changes via intercalation into 1D TMTs are not as simple as those in 2D transition metal dichalcogenides (TMDs) and are still not understood comprehensively. ZrTe3: a typical compound with a 1D trigonal prismatic structure, belongs to TMTs. Herein, through the Ag introduction to ZrTe3 via solid-state intercalation, a novel crystal phase with a 1D octahedral structure and a quasi-amorphous (QA) phase during the structural transition are discovered; the QA phase is a novel state of matter in which long-range order is lost while retaining 1D order. Based on the Ag concentration, the transport properties are flexibly modulated from superconductivity to semiconductivity. Density functional theory calculations indicate the attraction between Ag ions and the pair diffusion due to their attraction. Furthermore, judging the attraction or repulsion between guest ions predicts whether to induce a QA phase or simple lattice expansion like the intercalation into 2D TMDs. |
| Rights: | This is the peer reviewed version of the following article: [Fujioka, M., Jeem, M., Sato, K., Tanaka, M., Morita, K., Shibuya, T., Takahashi, K., Iwasaki, S., Miura, A., Nagao, M., Demura, S., Sakata, H., Ono, M., Kaiju, H., Nishii, J., Intercalation on Transition Metal Trichalcogenides via a Quasi-Amorphous Phase with 1D Order. Adv. Funct. Mater. 2023, 33, 2208702. https://doi.org/10.1002/adfm.202208702], which has been published in final form at https://doi.org/10.1002/adfm.202208702. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/91293 |
| Appears in Collections: | 電子科学研究所 (Research Institute for Electronic Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 藤岡 正弥
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