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Hokkaido University Collection of Scholarly and Academic Papers >
Institute for Chemical Reaction Design and Discovery : ICReDD >
Peer-reviewed Journal Articles, etc >
Multidynamic Crystalline Molecular Rotors Comprising an N-Heterocyclic Carbene Binuclear Au(I) Complex Bearing Multiple Rotators
| Title: | Multidynamic Crystalline Molecular Rotors Comprising an N-Heterocyclic Carbene Binuclear Au(I) Complex Bearing Multiple Rotators |
| Authors: | Jin, Mingoo Browse this author →KAKEN DB | | Matsuura, Satsuki Browse this author | | Yamamoto, Hikaru Browse this author | | Mizuno, Motohiro Browse this author | | Ito, Hajime Browse this author →KAKEN DB |
| Keywords: | correlated motion | | crystalline molecular rotor | | molecular dynamics | | multicomponent crystal | | NHC metal complex |
| Issue Date: | 21-Mar-2023 |
| Publisher: | Wiley-Blackwell |
| Journal Title: | European journal of organic chemistry |
| Volume: | 26 |
| Issue: | 12 |
| Start Page: | e202201468 |
| Publisher DOI: | 10.1002/ejoc.202201468 |
| Abstract: | We report multidynamic molecular rotations in crystals using a concave-shape N-heterocyclic carbene (NHC) binuclear Au(I) complex rotor bearing pyrazine and tetrahydrofuran (THF) molecules as multicomponent rotators. Single-crystal X-ray diffraction (XRD) measurements revealed that two THF molecules are located near the central pyrazine encapsulated by two bulky NHC ligands. From H-2 solid-state NMR analysis, it was observed that the pyrazine rotated in a 2-fold site exchange with a 180 degrees rotational angle and a 31 kJ mol(-1) energy barrier, while the THF molecules showed a 23 degrees-38 degrees libration with a lower energy barrier (14 kJ mol(-1)). Interestingly, the pyrazine rotation was accelerated when the THF molecules rotated in fast site exchange with a large angle of libration, suggesting that the rotators exhibit multidynamics in a correlated manner. |
| Rights: | This is the peer reviewed version of the following article: [Jin, M., Matsuura, S., Yamamoto, H., Mizuno, M., Ito, H., Eur. J. Org. Chem. 2023, 26, e202201468], which has been published in final form at https://doi.org/10.1002/ejoc.202201468. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/91734 |
| Appears in Collections: | 化学反応創成研究拠点：ICReDD (Institute for Chemical Reaction Design and Discovery : ICReDD) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 陳 旻究
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