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PANI sensor for monitoring the oxidative degradation of wine using cyclic voltammetry

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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/92751

Title: PANI sensor for monitoring the oxidative degradation of wine using cyclic voltammetry
Authors: Begum, Parvin Browse this author
Yang, Liu Browse this author
Morozumi, Tatsuya Browse this author →KAKEN DB
Sone, Teruo Browse this author →KAKEN DB
Kawaguchi, Toshikazu Browse this author →KAKEN DB
Keywords: Polyaniline sensor
Wine
Cyclic voltammetry
Degradation of wine
Issue Date: 15-Jul-2023
Journal Title: Food Chemistry
Volume: 414
Start Page: 135740
Publisher DOI: 10.1016/j.foodchem.2023.135740
Abstract: Redox species in wine are altered by pH and some wines are easily degraded due to oxidation and sulfur dioxide (SO2) reduction. There is a need for quick, easy, simple, and economical methodologies for pH and wine-oxidized products (acetaldehyde) analysis. This study aimed to measure pH and degradation of wines that were elec-trochemically analyzed using polyaniline (PANI) sensor. Gas chromatography (GC) and fourier transform infrared spectrometer (FT-IR) were also used. Electrochemical analysis showed that oxidation was accelerated and peak currents (Ip,a) and potentials (Ep,a) shifted to negative direction due to acetaldehyde formation. PANI sensor achieved a limit of detection (LOD) of 7 x 10-1 ppm and a sensitivity of 5.20 mu A ppm-1 cm-2. Acetal-dehyde formation was confirmed by GC (30%) and FT-IR spectra at 1647 cm-1 to the C--O vibration of aldehyde. These results suggested that acetaldehyde degraded the taste of wine after remaining open.
Rights: © 2023. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
https://creativecommons.org/licenses/by-nc-nd/4.0/
Type: article (author version)
URI: http://hdl.handle.net/2115/92751
Appears in Collections:環境科学院・地球環境科学研究院 (Graduate School of Environmental Science / Faculty of Environmental Earth Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 川口 俊一

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