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Infrared study of anomalous volume behavior of water–benzene mixtures in the vicinity of the critical region

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タイトル: Infrared study of anomalous volume behavior of water–benzene mixtures in the vicinity of the critical region
著者: Furutaka, Seiya 著作を一覧する
Ikawa, Shun-ichi 著作を一覧する
発行日: 2002年
出版者: American Institute of Physics
誌名: The Journal of Chemical Physics
巻: 117
号: 4
開始ページ: 1682
終了ページ: 1685
出版社 DOI: 10.1063/1.1488580
抄録: Volume behavior of water–benzene mixtures at temperatures and pressures in the 473–623 K and 100–350 bar ranges, respectively, has been studied by infrared in situ measurements. The densities of the benzene-rich phase were estimated from the spectroscopically determined concentrations of water and benzene and compared with the average densities before mixing, which were calculated using literature densities of neat water and neat benzene at the same temperature and pressure. Anomalously large volume change for mixing has been found in the vicinity of the critical region of the water–benzene mixtures.
Rights: Copyright © 2002 American Institute of Physics
Relation (URI): http://www.aip.org/
資料タイプ: article
URI: http://hdl.handle.net/2115/1397
出現コレクション:雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

提供者: 井川 駿一

 

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