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Photochemical fabrication of molecular devices

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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/14564

Title: Photochemical fabrication of molecular devices
Authors: Naito, Toshio Browse this author →KAKEN DB
Sugawara, Hideyuki Browse this author
Inabe, Tamotsu Browse this author
Miyamoto, Takeshi Browse this author
Niimi, Hironobu Browse this author
Asakura, Kiyotaka Browse this author
Keywords: Oxidation reduction
Electrical and electronic properties
Band structure
Conductivity
Optical spectroscopy
Photoinduced effects
XPS
Issue Date: 15-Jul-2006
Publisher: Elsevier B.V.
Journal Title: Journal of Non-Crystalline Solids
Volume: 352
Issue: 23-25
Start Page: 2628
Publisher DOI: 10.1016/j.jnoncrysol.2006.01.097
Abstract: We present a novel way to fabricate electronic devices from a molecular charge transfer salt Ag(DM)2 by simple illumination, which realizes a junction-structure in the single molecular crystal. The electrical conductivity of the selected parts of samples can be controlled by illimination time and power. The electrical behavior gradually turned semiconducting from metallic one by illumination. X-ray photoelectron spectroscopy, Raman spectroscopy and X-ray absorption fine structure indicated that illumination should transfer some electrons from the conducting DM columns to the Ag ions. The X-ray powder diffraction pattern indicated that original crystal lattice was maintained after the illumination. These observations imply that the illumination practically effected doping (or rather dedoping) on the material.
Relation: http://www.sciencedirect.com/science/journal/00223093
Type: article (author version)
URI: http://hdl.handle.net/2115/14564
Appears in Collections:理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 内藤 俊雄

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