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Reaction of CS2/Cl complexes with alcohols studied by pulse radiolysis

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Title: Reaction of CS2/Cl complexes with alcohols studied by pulse radiolysis
Authors: Sumiyoshi, Takashi Browse this author →KAKEN DB
Nakayama, Masayosi Browse this author
Fujiyoshi, Ryoko Browse this author
Sawamura, Sadashi Browse this author
Keywords: CS2/Cl complex
Hydrogen abstraction
Selectivity
Pulse radiolysis
Issue Date: Dec-2005
Publisher: Elsevier
Journal Title: Radiation Physics and Chemistry
Volume: 74
Issue: 5
Start Page: 317
End Page: 322
Publisher DOI: 10.1016/j.radphyschem.2005.02.008
Abstract: The reactivity and selectivity of carbon disulfide-chlorine atom complex (CS2/Cl) for hydrogen atom abstraction from various alcohols were studied by pulse radiolysis technique in carbon tetrachloride at room temperature. The measured absolute rate constants were in the range from 4.0×106 for methanol to 3.5×107 dm3 mol−1 s−1 for cyclopentanol. The hydrogen abstraction selectivity was calculated based on the analysis of partial reactivities. The tertiary/primary selectivities were determined to be 8.2 for α-position and 6.8 for β-position of alcohols.
Relation: http://www.sciencedirect.com/science/journal/0969806X
Type: article (author version)
URI: http://hdl.handle.net/2115/15413
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 住吉 孝

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