HUSCAP logo Hokkaido Univ. logo

Hokkaido University Collection of Scholarly and Academic Papers >
Graduate School of Engineering / Faculty of Engineering >
Peer-reviewed Journal Articles, etc >

Photochemistry of CS2/Cl complexes-combined pulse radiolysis-laser flash photolysis studies

Files in This Item:
RPC75-1.pdf257.13 kBPDFView/Open
Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/15415

Title: Photochemistry of CS2/Cl complexes-combined pulse radiolysis-laser flash photolysis studies
Authors: Sumiyoshi, Takashi Browse this author →KAKEN DB
Nakayama, Masayoshi Browse this author
Fujiyoshi, Ryoko Browse this author
Sawamura, Sadashi Browse this author
Keywords: CS2/Cl complex
Pulse radiolysis
Laser flash photolysis
Intermolecular hydrogen abstraction
Issue Date: Jan-2006
Publisher: Elsevier
Journal Title: Radiation Physics and Chemistry
Volume: 75
Issue: 1
Start Page: 20
End Page: 25
Publisher DOI: 10.1016/j.radphyschem.2005.06.002
Abstract: Complexes of chlorine atoms and carbon disulfide (CS2) were produced by pulse radiolysis of CS2 in halocarbons and photochemical reactions were studied by laser flash photolysis. Excitation of CS2/Cl complexes resulted in rapid and permanent photobleaching. The photobleaching of CS2/Cl complexes is due to intermolecular chlorine atom abstraction in CCl4 with a quantum yield of 0.04, while that ascribed to hydrogen atom abstraction in 1,2-dichloroethane has a quantum yield of 0.21. The effects of additives are discussed based on the bond dissociation energy.
Relation: http://www.sciencedirect.com/science/journal/0969806X
Type: article (author version)
URI: http://hdl.handle.net/2115/15415
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 住吉 孝

Export metadata:

OAI-PMH ( junii2 , jpcoar )

MathJax is now OFF:


 

 - Hokkaido University