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A comparative study of supported aqueous- and ethylene glycol-phase catalysts in stilbene hydrogenation: Influence of the different modes of dispersion of supported liquids

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Title: A comparative study of supported aqueous- and ethylene glycol-phase catalysts in stilbene hydrogenation: Influence of the different modes of dispersion of supported liquids
Authors: Fujita, Shin-ichiro Browse this author →KAKEN DB
Sano, Yoko Browse this author
Bhanage, Balchandra M. Browse this author
Arai, Masahiko Browse this author →KAKEN DB
Keywords: Supported liquid phase catalyst
Metal complex
Hydrogenation
Catalyst preparation
Palladium
Issue Date: 25-Oct-2006
Publisher: Elsevier B.V.
Journal Title: Applied Catalysis A General
Volume: 314
Issue: 1
Start Page: 89
End Page: 93
Publisher DOI: 10.1016/j.apcata.2006.08.006
Abstract: Supported liquid phase catalysts (SLPC) containing water-soluble Pd complexes were used for hydrogenation of stilbene in toluene. When water is loaded on a silica gel support, the catalytic activity of SLPC increases with the amount of the water. In contrast, when ethylene glycol (EG) is used as the supported liquid, the activity does not depend on the amount of EG loaded. These results can be explained by differences in the mode of dispersion of the supported liquids over the support.
Relation: http://www.sciencedirect.com/science/journal/0926860X
Type: article (author version)
URI: http://hdl.handle.net/2115/15831
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 藤田 進一郎

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