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Dirhodium(II) tetrakis(perfluorobutyrate)-catalyzed 1,4-hydrosilylation of α,β-unsaturated carbonyl compounds
| Title: | Dirhodium(II) tetrakis(perfluorobutyrate)-catalyzed 1,4-hydrosilylation of α,β-unsaturated carbonyl compounds |
| Authors: | Anada, Masahiro Browse this author →KAKEN DB | | Tanaka, Masahiko Browse this author | | Suzuki, Kanami Browse this author | | Nambu, Hisanori Browse this author →KAKEN DB | | Hashimoto, Shunichi Browse this author →KAKEN DB |
| Keywords: | dirhodium(II) complex | | 1,4-hydrosilylation | | silyl enol ether | | α,β-enone |
| Issue Date: | Nov-2006 |
| Publisher: | 社団法人 日本薬学会 |
| Journal Title: | CHEMICAL & PHARMACEUTICAL BULLETIN |
| Volume: | 54 |
| Issue: | 11 |
| Start Page: | 1622 |
| End Page: | 1623 |
| Publisher DOI: | 10.1248/cpb.54.1622 |
| PMID: | 17077568 |
| Abstract: | The use of dirhodium(II) catalysts in the 1,4-hydrosilylation of α,β-unsaturthis process, providing the corresponding silyl enol ethers in high yields.ated ketones and aldehydes was explored. Dirhodium(II) tetrakis(perfluorobutyrate), Rh2(pfb)4' proved to be the catalyst of choice for this process, providing the corresponding silyl enol ethers in high yields. |
| Type: | article |
| URI: | http://hdl.handle.net/2115/17095 |
| Appears in Collections: | 薬学研究院 (Faculty of Pharmaceutical Sciences) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 橋本 俊一
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