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Dirhodium(II) tetrakis(perfluorobutyrate)-catalyzed 1,4-hydrosilylation of α,β-unsaturated carbonyl compounds

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Title: Dirhodium(II) tetrakis(perfluorobutyrate)-catalyzed 1,4-hydrosilylation of α,β-unsaturated carbonyl compounds
Authors: Anada, Masahiro Browse this author →KAKEN DB
Tanaka, Masahiko Browse this author
Suzuki, Kanami Browse this author
Nambu, Hisanori Browse this author →KAKEN DB
Hashimoto, Shunichi Browse this author →KAKEN DB
Keywords: dirhodium(II) complex
1,4-hydrosilylation
silyl enol ether
α,β-enone
Issue Date: Nov-2006
Publisher: 社団法人 日本薬学会
Journal Title: CHEMICAL & PHARMACEUTICAL BULLETIN
Volume: 54
Issue: 11
Start Page: 1622
End Page: 1623
Publisher DOI: 10.1248/cpb.54.1622
PMID: 17077568
Abstract: The use of dirhodium(II) catalysts in the 1,4-hydrosilylation of α,β-unsaturthis process, providing the corresponding silyl enol ethers in high yields.ated ketones and aldehydes was explored. Dirhodium(II) tetrakis(perfluorobutyrate), Rh2(pfb)4' proved to be the catalyst of choice for this process, providing the corresponding silyl enol ethers in high yields.
Type: article
URI: http://hdl.handle.net/2115/17095
Appears in Collections:薬学研究院 (Faculty of Pharmaceutical Sciences) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 橋本 俊一

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