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Oxidation behavior of Mo-Si-B in-situ Composites
Title: | Oxidation behavior of Mo-Si-B in-situ Composites |
Authors: | Yamauchi, Akira Browse this author | Yoshimi, Kyosuke Browse this author | Murakami, Yoshihiro Browse this author | Kurokawa, Kazuya Browse this author →KAKEN DB | Hanada, Shuji Browse this author |
Keywords: | molybdenum silicides | in-situ composite | high temperature oxidation | borosilicate |
Issue Date: | 2007 |
Publisher: | Trans Tech Publications |
Journal Title: | Designing of Interfacial Structures (Solid State Phenomena: 127) |
Start Page: | 215 |
End Page: | 220 |
Abstract: | Isothermal oxidation behavior of Al added Mo-Si-B in-situ composites was investigated under Ar-20%O2 and air atmosphere over the temperature range of 1073–1673 K. The Al added Mo-Si-B composites ((Mo-8.7mol%Si-17.4mol%B)-1mol%Al) were prepared by arc-melting, and homogenized at 2073 K for 24 h in an Ar-flow atmosphere. The ternary Mo-Si-B in-situ composite exhibited a rapid mass loss at the initial oxidation stage and then the passive oxidation after the substrates were sealed with borosilicate glass in the temperature range of 1173–1473 K, whereas it exhibited a rapid mass gain around 1073 K. On the other hand, the Al addition significantly improved the oxidation resistance of Mo-Si-B in-situ composites at temperatures from 1073–1573 K. These excellent oxidation resistances are considered to be due to the rapid formation of a continuous, dense scale of Al-Si-O complex oxides. |
Description: | Proceedings of the International Workshop on Designing of Interfacial Structures in Advanced Materials and their Joints, May, 18-20, 2006, held in Osaka, Japan |
Rights: | the original is available online at www.scientific.net |
Type: | article (author version) |
URI: | http://hdl.handle.net/2115/17157 |
Appears in Collections: | エネルギー・マテリアル融合領域研究センター (Center for Advanced Research of Energy and Material) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 山内 啓
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