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Catalytic Enantioselective Aziridination of Alkenes Using Chiral Dirhodium(II) Carboxylates

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Title: Catalytic Enantioselective Aziridination of Alkenes Using Chiral Dirhodium(II) Carboxylates
Authors: Yamawaki, Minoru Browse this author
Tanaka, Masahiko Browse this author
Abe, Takumi Browse this author
Anada, Masahiro Browse this author →KAKEN DB
Hashimoto, Shunichi Browse this author →KAKEN DB
Issue Date: 13-Apr-2007
Publisher: The Japan Institute of Heterocyclic Chemistry
Journal Title: Heterocycles - An International Journal for Reviews and Communications in Heterocyclic Chemistry
Volume: 72
Start Page: 709
End Page: 721
Abstract: The enantioselective aziridination of alkenes with [N-(4-nitrophenylsulfonyl)imino]phenyliodinane catalyzed by dirhodium(II) tetrakis[N-tetrachlorophthaloyl-(S)-tert-leucinate], Rh2(S-TCPTTL)4, is described. While such enantioselectivities are highly dependent on the properties of the alkenes, 2,2-dimethylchromene was found to be a particularly suitable substrate which can be efficiently transformed into the aziridine product in 98% yield with 94% ee.
Type: article (author version)
Appears in Collections:薬学研究院 (Faculty of Pharmaceutical Sciences) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 穴田 仁洋

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