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Peer-reviewed Journal Articles, etc >
Catalytic Enantioselective Aziridination of Alkenes Using Chiral Dirhodium(II) Carboxylates
| Title: | Catalytic Enantioselective Aziridination of Alkenes Using Chiral Dirhodium(II) Carboxylates |
| Authors: | Yamawaki, Minoru Browse this author | | Tanaka, Masahiko Browse this author | | Abe, Takumi Browse this author | | Anada, Masahiro Browse this author →KAKEN DB | | Hashimoto, Shunichi Browse this author →KAKEN DB |
| Issue Date: | 13-Apr-2007 |
| Publisher: | The Japan Institute of Heterocyclic Chemistry |
| Journal Title: | Heterocycles - An International Journal for Reviews and Communications in Heterocyclic Chemistry |
| Volume: | 72 |
| Start Page: | 709 |
| End Page: | 721 |
| Abstract: | The enantioselective aziridination of alkenes with [N-(4-nitrophenylsulfonyl)imino]phenyliodinane catalyzed by dirhodium(II) tetrakis[N-tetrachlorophthaloyl-(S)-tert-leucinate], Rh2(S-TCPTTL)4, is described. While such enantioselectivities are highly dependent on the properties of the alkenes, 2,2-dimethylchromene was found to be a particularly suitable substrate which can be efficiently transformed into the aziridine product in 98% yield with 94% ee. |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/26427 |
| Appears in Collections: | 薬学研究院 (Faculty of Pharmaceutical Sciences) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 穴田 仁洋
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