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Practical Synthesis of Dirhodium (II) Tetrakis[N-phthaloyl-(S)-tert-leucinate]

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Title: Practical Synthesis of Dirhodium (II) Tetrakis[N-phthaloyl-(S)-tert-leucinate]
Authors: Tsutsui, Hideyuki Browse this author
Abe, Takumi Browse this author
Nakamura, Seiichi Browse this author
Anada, Masahiro Browse this author →KAKEN DB
Hashimoto, Shunichi Browse this author →KAKEN DB
Keywords: tert-leucine
chiral catalyst
Issue Date: 1-Oct-2005
Publisher: 社団法人 日本薬学会
Journal Title: Chemical & pharmaceutical bulletin
Volume: 53
Issue: 10
Start Page: 1366
End Page: 1368
Abstract: An efficient and reliable procedure for the preparation of dirhodium(II) tetrakis[N-phthaloyl-(S)-tert-leuci-nate], Rh_2(S-PTTL)_4, a universally effective catalyst for a range of enantioselective carbene transformations, is described. The N-phthaloylation of (S)-tert-leucine by the method of Bose with essentially no racemization is a key to this process.
Type: article
Appears in Collections:薬学研究院 (Faculty of Pharmaceutical Sciences) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 穴田 仁洋

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