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Hokkaido University Collection of Scholarly and Academic Papers >
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Photochemical Method of Device Fabrication Starting from Molecular Crystals
| Title: | Photochemical Method of Device Fabrication Starting from Molecular Crystals |
| Authors: | Naito, Toshio Browse this author →KAKEN DB | | Sugawara, Hideyuki Browse this author | | Inabe, Tamotsu Browse this author | | Miyamoto, Takeshi Browse this author | | Niimi, Hironobu Browse this author | | Asakura, Kiyotaka Browse this author |
| Keywords: | charge-transfer | | doping | | molecular semiconductor-metal junction | | N,N’-dicyanoquinonediimine | | photo-induced phenomena |
| Issue Date: | Oct-2006 |
| Publisher: | Taylor & Francis |
| Journal Title: | Molecular Crystals and Liquid Crystals |
| Volume: | 455 |
| Issue: | 1 |
| Start Page: | 311 |
| End Page: | 316 |
| Publisher DOI: | 10.1080/15421400600699012 |
| Abstract: | The conductivity of a silver salt of N,N'-dicyanoquinonediimine irreversibly varied in approximate proportion to an illumination of a wide range of wavelengths. Depending on the illumination conditions, four different states (β, γ, δ, and ε) were obtained with different structures. The β structure is in particular important, where the formal charge of the N,N'-dicyanoquinonediimine molecules continuously decreased to -0.4--0.35 with retaining the crystal structure, when we kept the temperature <155°C during the illumination. The non-illuminated area of the sample retained its original electrical property with a well-defined interface, which enabled a fabrication of a junction-structure in the single crystal. |
| Rights: | This is an electronic version of an article published in Naito, T; Sugawara, H; Inabe, T; Miyamoto, T; Niimi, H; Asakura, K, Photochemical method of device fabrication starting from molecular crystals, MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 455(1), Oct. 2006, pp. 311-316. MOLECULAR CRYSTALS AND LIQUID CRYSTALS is available online at: http://www.informaworld.com/ |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/30130 |
| Appears in Collections: | 理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 内藤 俊雄
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