Stereoselective synthesis of 4-fluoro-1,3-alkadienylboronates and their application in the stereoselective synthesis of fluoropolyenes


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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/30291

Title:	Stereoselective synthesis of 4-fluoro-1,3-alkadienylboronates and their application in the stereoselective synthesis of fluoropolyenes
Authors:	Sakai, Miho Browse this author
	Guan, Tong Browse this author
	Hara, Shoji Browse this author →KAKEN DB
Keywords:	Heck-reaction
	Fluoroalkadienylboronates
	Suzuki–Miyaura coupling
	Fluoropolyene
	Fluoroalkenyliodonium salts
Issue Date:	Dec-2007
Publisher:	Elsevier B.V.
Journal Title:	Journal of Fluorine Chemistry
Volume:	128
Issue:	12
Start Page:	1444
End Page:	1448
Publisher DOI:	10.1016/j.jfluchem.2007.07.009
Abstract:	(1E,3E)- and (1E,3Z)-4-fluoro-1,3-alkadienylboronates were stereoselectively prepared by the Heck-reaction of a vinylboronate with (E)- or (Z)-2-fluoro-1-alkenyliodonium salts, and applied to the Suzuki–Miyaura coupling reaction for the synthesis of fluoropolyenes.
Relation:	http://www.sciencedirect.com/science/journal/00221139
Type:	article (author version)
URI:	http://hdl.handle.net/2115/30291
Appears in Collections:	工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 原正治

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