|
Hokkaido University Collection of Scholarly and Academic Papers >
Graduate School of Engineering / Faculty of Engineering >
Peer-reviewed Journal Articles, etc >
Fluorination of alcohols and diols with a novel fluorous deoxy-fluorination reagent
| Title: | Fluorination of alcohols and diols with a novel fluorous deoxy-fluorination reagent |
| Authors: | Furuya, Tsukasa Browse this author | | Nomoto, Takashi Browse this author | | Fukuhara, Tsuyoshi Browse this author | | Hara, Shoji Browse this author →KAKEN DB |
| Keywords: | Fluorous fluorination reagent | | Deoxy-fluorination reaction | | N,N-Diethyl-α,α-difluoro-[3,5-bis(1H,1H,2H,2H-perfluorodecyl)benzyl]amine |
| Issue Date: | Mar-2009 |
| Publisher: | Elsevier |
| Journal Title: | Journal of Fluorine Chemistry |
| Volume: | 130 |
| Issue: | 3 |
| Start Page: | 348 |
| End Page: | 353 |
| Publisher DOI: | 10.1016/j.jfluchem.2008.12.010 |
| Abstract: | We prepared a novel fluorous deoxy-fluorination reagent N,N-diethyl-α,α-difluoro-[3,5-bis(1H,1H,2H,2H-perfluorodecyl)benzyl]amine (1b) from 3,5-diiodobenzoic acid (3b) via N,N-diethyl-3,5-bis(1H,1H,2H,2H-perfluorodecyl)benzamide (2b) in four steps and used it for the fluorination of alcohols and diols. After the fluorination reactions, the isolation of the products and recovery of 2b was performed by extraction with a fluorous/organic solvent system. |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/36636 |
| Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
|
Submitter: 原 正治
|
