Facile Synthesis of Bicyclo Orthoesters and Bicyclo Amide Acetals Using α,α-Difluoroalkylamines


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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/39536

Title:	Facile Synthesis of Bicyclo Orthoesters and Bicyclo Amide Acetals Using α,α-Difluoroalkylamines
Authors:	Tange, Seiko Browse this author
	Fukuhara, Tsuyoshi Browse this author
	Hara, Shoji Browse this author →KAKEN DB
Keywords:	bicyclo orthoesters
	bicyclo amide acetals
	α,α-difluoroalkylamines
	protecting group
	polymer
Issue Date:	17-Oct-2008
Publisher:	Georg Thieme Verlag
Journal Title:	Synthesis
Volume:	2008
Issue:	20
Start Page:	3219
End Page:	3222
Publisher DOI:	10.1055/s-0028-1083145
Abstract:	Bicyclo orthoesters and amide acetals were prepared from the corresponding triols or diethanolamine using α,α-difluoroalkylamines. The reaction proceeds under milder conditions compared with the conventional methods. 4-tert-Butyl-1-(4-ethynylphenyl)trioxabicyclo[2.2.2]octane, a new class of insecticide, was prepared from a triol in 3 steps using a difluoroalkylamine.
Rights:	© 2008 Georg Thieme Verlag
Type:	article (author version)
URI:	http://hdl.handle.net/2115/39536
Appears in Collections:	工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 原正治

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