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Electronic phase diagram of the layered cobalt oxide system LixCoO2 (0.0 ≤ x ≤ 1.0)

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タイトル: Electronic phase diagram of the layered cobalt oxide system LixCoO2 (0.0 ≤ x ≤ 1.0)
著者: Motohashi, T. 著作を一覧する
Ono, T. 著作を一覧する
Sugimoto, Y. 著作を一覧する
Masubuchi, Y. 著作を一覧する
Kikkawa, S. 著作を一覧する
Kanno, R. 著作を一覧する
Karppinen, M. 著作を一覧する
Yamauchi, H. 著作を一覧する
キーワード: antiferromagnetic materials
charge-ordered states
electron correlations
lithium compounds
magnetic susceptibility
magnetic transitions
nuclear quadrupole resonance
発行日: 2009年10月
出版者: American Physical Society
誌名: Physical Review B
巻: 80
号: 16
開始ページ: 165114
出版社 DOI: 10.1103/PhysRevB.80.165114
抄録: Here we report the magnetic properties of the layered cobalt oxide system, LixCoO2, in the whole range of Li composition, 0 ≤ x ≤ 1. Based on dc-magnetic-susceptibility data, combined with results of Co-59 nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) observations, the electronic phase diagram of LixCoO2 has been established. As in the related material NaxCoO2, a magnetic critical point is found to exist between x=0.35 and 0.40, which separates the Pauli-paramagnetic and Curie-Weiss metals. In the Pauli-paramagnetic regime (x ≤ 0.35), the antiferromagnetic spin correlations systematically increase with decreasing x. Nevertheless, CoO2, the x=0 end member is a noncorrelated metal in the whole temperature range studied. In the Curie-Weiss regime (x ≥ 0.40), on the other hand, various phase transitions are observed. For x=0.40, a susceptibility hump is seen at 30 K, suggesting the onset of static antiferromagnetic order. A magnetic jump, which is likely to be triggered by charge ordering, is clearly observed at T-t ≈ 175 K in samples with x=0.50 (=1/2) and 0.67 (=2/3), while only a tiny kink appears at T ≈ 210 K in the sample with an intermediate Li composition, x=0.60. Thus, the phase diagram of the LixCoO2 system is complex and the electronic properties are sensitively influenced by the Li content (x).
Rights: © 2009 The American Physical Society
資料タイプ: article
出現コレクション:雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

提供者: 本橋 輝樹


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