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Dielectric study of acetophenone and its derivatives

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Title: Dielectric study of acetophenone and its derivatives
Authors: Yomogida, Yoshiki Browse this author
Nozaki, Ryusuke Browse this author
Keywords: Dielectric relaxation
Hydrogen-bonded liquids
Molecular dynamics
Issue Date: 30-Oct-2009
Publisher: Elsevier B.V.
Journal Title: Journal of Molecular Liquids
Volume: 149
Issue: 3
Start Page: 101
End Page: 104
Publisher DOI: 10.1016/j.molliq.2009.09.001
Abstract: Complex permittivity measurements on acetophenone and its derivatives o-hydroxybenzaldehyde, o-methylacetophenone, and o-hydroxyacetophenone are performed at frequencies between 1 MHz and 20 GHz at temperatures from 273 to 323 K. The parameters obtained from the fitting of the complex permittivity are analyzed in order to study the effects of the hydroxyl group within a molecule on the dielectric relaxation phenomenon in these liquids. The analysis indicates that dynamical properties are affected not only by the intermolecular hydrogen bond but also by the slight change in molecular structure. This conclusion differs from those obtained from the results of other experiments.
Type: article (author version)
URI: http://hdl.handle.net/2115/39955
Appears in Collections:理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 野嵜 龍介

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