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Ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron catalyzed by iridium-phosphine complexes

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Title: Ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron catalyzed by iridium-phosphine complexes
Authors: Ishiyama, Tatsuo Browse this author →KAKEN DB
Isou, Hironori Browse this author
Kikuchi, Takao Browse this author
Miyaura, Norio Browse this author →KAKEN DB
Issue Date: 7-Jan-2010
Publisher: Royal Society of Chemistry
Journal Title: Chemical Communications
Volume: 46
Issue: 1
Start Page: 159
End Page: 161
Publisher DOI: 10.1039/b910298a
PMID: 20024326
Abstract: Iridium complexes generated from [Ir(OMe)(COD)]2 and tris[3,5-bis(trifluoromethyl)phenyl]phosphine efficiently catalyzed the ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron in octane at 80℃ to produce the corresponding arylboronates in high yields with excellent regioselectivities.
Rights: Chem. Commun., 2010, 46, 159-161 - Reproduced by permission of The Royal Society of Chemistry (RSC)
Type: article (author version)
URI: http://hdl.handle.net/2115/44631
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 石山 竜生

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