Ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron catalyzed by iridium-phosphine complexes


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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/44631

Title:	Ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron catalyzed by iridium-phosphine complexes
Authors:	Ishiyama, Tatsuo Browse this author →KAKEN DB
	Isou, Hironori Browse this author
	Kikuchi, Takao Browse this author
	Miyaura, Norio Browse this author →KAKEN DB
Issue Date:	7-Jan-2010
Publisher:	Royal Society of Chemistry
Journal Title:	Chemical Communications
Volume:	46
Issue:	1
Start Page:	159
End Page:	161
Publisher DOI:	10.1039/b910298a
PMID:	20024326
Abstract:	Iridium complexes generated from [Ir(OMe)(COD)]2 and tris[3,5-bis(trifluoromethyl)phenyl]phosphine efficiently catalyzed the ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron in octane at 80℃ to produce the corresponding arylboronates in high yields with excellent regioselectivities.
Rights:	Chem. Commun., 2010, 46, 159-161 - Reproduced by permission of The Royal Society of Chemistry (RSC)
Type:	article (author version)
URI:	http://hdl.handle.net/2115/44631
Appears in Collections:	工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 石山竜生

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