Asymmetric Hydrogenation of Aromatic Heterocyclic Ketones Catalyzed by the MsDPEN–Cp*Ir(III) Complex


Hokkaido University \| Library \| HUSCAP	Advanced Search		言語

	Home
	About HUSCAP
	Open Access Policy

	Browse by Author

Browse
	Communities & Collections

	Scholarly Journals
	Theses
	Doctoral Dissertations Listed by Graduate Schools
	Conference Procs.
	Events

	HUSCAP Senior (in Japanese)

	Societies

	Downloads (country)

For university staff
	How to post your papers to HUSCAP
	Publication of theses
	Helpline about theses publication

Open Archives Compliant

You can search our collection also at:
	Google
	Google Scholar
	CiNii
	IRDB
	OAIster
	NDLTD

Files in This Item:

Het80-1_141-147.pdf

260.04 kB

PDF

Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/45011

Title:	Asymmetric Hydrogenation of Aromatic Heterocyclic Ketones Catalyzed by the MsDPEN–Cp*Ir(III) Complex
Authors:	Utsumi, Noriyuki Browse this author
	Tsutsumi, Kunihiko Browse this author
	Watanabe, Masahiko Browse this author
	Murata, Kunihiko Browse this author
	Arai, Noriyoshi Browse this author
	Kurono, Nobuhito Browse this author
	Ohkuma, Takeshi Browse this author
Keywords:	Asymmetric Hydrogenation
	Chiral Alchohol
	Enantioselective Reaction
	Iridium Catalyst
	Ketone
Issue Date:	1-Jan-2010
Publisher:	Japan Institute of Heterocyclic Chemistry
Journal Title:	Heterocycles
Volume:	80
Issue:	1
Start Page:	141
End Page:	147
Publisher DOI:	10.3987/COM-09-S(S)34
Abstract:	Asymmetric hydrogenation of aromatic heterocyclic ketones catalyzed by Cp*Ir(OTf)(Msdpen) (MsDPEN = N-(methanesulfonyl)-1,2-diphenylethylenediamine) affords the heterocyclic alcohols in 93% to > 99% ee. The reaction is conducted in a methanolic solution with a substrate-to-catalyst molar ratio of 200-5000 under 15 atm of H2. The heterocyclic rings of substrates are left intact.
Type:	article (author version)
URI:	http://hdl.handle.net/2115/45011
Appears in Collections:	工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 大熊毅

OAI-PMH ( junii2 , jpcoar_1.0 )

- Hokkaido University