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In situ transmission electron microscopy observation of the decomposition of MgH2 nanofiber
Title: | In situ transmission electron microscopy observation of the decomposition of MgH2 nanofiber |
Authors: | Zhu, Chunyu Browse this author | Sakaguchi, Norihito Browse this author | Hosokai, Sou Browse this author | Watanabe, Seiichi Browse this author | Akiyama, Tomohiro Browse this author |
Keywords: | Hydrogen storage | Magnesium hydride | Nanofiber | Hydriding chemical vapor deposition | TEM |
Issue Date: | Mar-2011 |
Publisher: | Elsevier |
Journal Title: | International Journal of Hydrogen Energy |
Volume: | 36 |
Issue: | 5 |
Start Page: | 3600 |
End Page: | 3605 |
Publisher DOI: | 10.1016/j.ijhydene.2010.12.017 |
Abstract: | In this paper, we presented an investigation of the phase transformation of MgH2 to Mg, in which a sample of a single-crystal MgH2 nanofiber was prepared by hydriding chemical vapor deposition (HCVD) and observed by in situ (high-resolution) transmission electron microscopy (TEM). The results indicated that the orientation relationship between MgH2 and Mg during the phase change was: one of the zone axis of MgH2 <110> parallel to Mg [0001] zone axis, or one of the plane {110} of MgH2 parallel to the basal plane of Mg (0001). On the basis of the obtained results, we proposed a structural model for the phase change of MgH2 to Mg. |
Type: | article (author version) |
URI: | http://hdl.handle.net/2115/45175 |
Appears in Collections: | エネルギー・マテリアル融合領域研究センター (Center for Advanced Research of Energy and Material) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 朱 春宇
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