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Ru/Me-BIPAM-Catalyzed Asymmetric Addition of Arylboronic Acids to Aliphatic Aldehydes and α-Ketoesters

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Title: Ru/Me-BIPAM-Catalyzed Asymmetric Addition of Arylboronic Acids to Aliphatic Aldehydes and α-Ketoesters
Authors: Yamamoto, Yasunori Browse this author
Shirai, Tomohiko Browse this author
Watanabe, Momoko Browse this author
Kurihara, Kazunori Browse this author
Miyaura, Norio Browse this author
Keywords: asymmetric catalyst
bidentate phosphoramidite ligand
ruthenium catalyzed arylation
Issue Date: Jun-2011
Publisher: MDPI Publishing
Journal Title: Molecules
Volume: 16
Issue: 6
Start Page: 5020
End Page: 5034
Publisher DOI: 10.3390/molecules16065020
Abstract: A ruthenium-catalyzed asymmetric arylation of aliphatic aldehydes and α-ketoesters with arylboronic acids has been developed, giving chiral alkyl(aryl)methanols and α-hydroxy esters in good yields. The use of a chiral bidentate phosphoramidite ligand (Me-BIPAM) achieved excellent enantioselectivities.
Rights: http://creativecommons.org/licenses/by/3.0/
Type: article
URI: http://hdl.handle.net/2115/46792
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 山本 靖典

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