Novel Synthesis of Optically Active Bishomotyrosine Derivatives Using the Friedel-Crafts Reaction in Triflic Acid


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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/47098

Title:	Novel Synthesis of Optically Active Bishomotyrosine Derivatives Using the Friedel-Crafts Reaction in Triflic Acid
Authors:	Murai, Yuta Browse this author
	Hashidoko, Yasuyuki Browse this author
	Hashimoto, Makoto Browse this author
Keywords:	bishomotyrosine
	phenol
	Friedel-Crafts reaction
	Fries rearrangement
	triflic acid
Issue Date:	2011
Publisher:	Japan Society for Bioscience, Biotechnology, and Agrochemistry
Journal Title:	Bioscience, Biotechnology, and Biochemistry
Volume:	75
Issue:	2
Start Page:	352
End Page:	354
Publisher DOI:	10.1271/bbb.100595
Abstract:	We report here a novel synthesis of optically active bishomotyrosine. The bishomotyrosine skeleton was constructed by using a Friedel-Crafts reaction between phenol and optically active N-Tfa-Glu(Cl)-OMe in triflic acid under the mild condition. Reduction and subsequent deprotection then afforded bishomotyrosine derivatives without any loss of optical purity.
Type:	article
URI:	http://hdl.handle.net/2115/47098
Appears in Collections:	農学院・農学研究院 (Graduate School of Agriculture / Faculty of Agriculture) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 橋本誠

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