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An effective medium of H2O and low-pressure CO2 for the selective hydrogenation of aromatic nitro compounds to anilines
Title: | An effective medium of H2O and low-pressure CO2 for the selective hydrogenation of aromatic nitro compounds to anilines |
Authors: | Meng, Xiangchun Browse this author | Cheng, Haiyang Browse this author | Fujita, Shin-ichiro Browse this author | Yu, Yancun Browse this author | Zhao, Fengyu Browse this author | Arai, Masahiko Browse this author →KAKEN DB |
Issue Date: | Mar-2011 |
Publisher: | Royal Society of Chemistry |
Journal Title: | Green Chemistry |
Volume: | 13 |
Issue: | 3 |
Start Page: | 570 |
End Page: | 572 |
Publisher DOI: | 10.1039/c0gc00246a |
Abstract: | Chemoselective hydrogenation of water-insoluble aromatic nitro compounds can be achieved over Ni catalysts in a H2O-compressed CO2 system at 35-50℃ without using any environmentally harmful solvent. The effective CO2 pressure is much lower than the critical pressure of CO2. The hydrogenation of nitro group should be the rate-determining step. |
Rights: | Green Chem., 2011, 13, 570-572 - Reproduced by permission of The Royal Society of Chemistry (RSC) |
Type: | article (author version) |
URI: | http://hdl.handle.net/2115/47798 |
Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 荒井 正彦
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