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An effective medium of H2O and low-pressure CO2 for the selective hydrogenation of aromatic nitro compounds to anilines

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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/47798

Title: An effective medium of H2O and low-pressure CO2 for the selective hydrogenation of aromatic nitro compounds to anilines
Authors: Meng, Xiangchun Browse this author
Cheng, Haiyang Browse this author
Fujita, Shin-ichiro Browse this author
Yu, Yancun Browse this author
Zhao, Fengyu Browse this author
Arai, Masahiko Browse this author →KAKEN DB
Issue Date: Mar-2011
Publisher: Royal Society of Chemistry
Journal Title: Green Chemistry
Volume: 13
Issue: 3
Start Page: 570
End Page: 572
Publisher DOI: 10.1039/c0gc00246a
Abstract: Chemoselective hydrogenation of water-insoluble aromatic nitro compounds can be achieved over Ni catalysts in a H2O-compressed CO2 system at 35-50℃ without using any environmentally harmful solvent. The effective CO2 pressure is much lower than the critical pressure of CO2. The hydrogenation of nitro group should be the rate-determining step.
Rights: Green Chem., 2011, 13, 570-572 - Reproduced by permission of The Royal Society of Chemistry (RSC)
Type: article (author version)
URI: http://hdl.handle.net/2115/47798
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 荒井 正彦

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