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Low-temperature fabrication of BaBi2Nb2O9 ceramics by reaction controlled sintering
Title: | Low-temperature fabrication of BaBi2Nb2O9 ceramics by reaction controlled sintering |
Authors: | Shigyo, Tatsuhiro Browse this author | Itoh, Hidenobu Browse this author | Takahashi, Junichi Browse this author →KAKEN DB |
Keywords: | BaBi2Nb2O9 | reaction controlled sintering | low-temperature sintering | phase formation | densification |
Issue Date: | Mar-2010 |
Publisher: | Springer New York |
Journal Title: | Journal of Materials Science: Materials in Electronics |
Volume: | 21 |
Issue: | 3 |
Start Page: | 302 |
End Page: | 308 |
Publisher DOI: | 10.1007/s10854-009-9910-7 |
Abstract: | Reaction controlled sintering was applied to the fabrication of BaBi2Nb2O9 (BBN) ceramics at lower temperature. A powder mixture of BaCO3 and Nb2O5 was heated at 600℃ in a 1st step calcination to produce a binary precursor of BaNb2O6. The pre-heated powder was then mixed with a fixed amount of Bi2O3, which was subsequently pressed into a disk pellet. After a powder compact of the mixture was subjected to heating at 950℃ for 4 h, a BBN bulk sample with a relative density of 92% was successfully obtained. The low-temperature fabrication of dense BBN ceramics could be attributed to the inhibited formation of an intermediate phase of Ba5Nb4O15 and the production of submicron powder with an appropriate reactivity during a 1st step calcination. |
Rights: | The final publication is available at www.springerlink.com |
Type: | article (author version) |
URI: | http://hdl.handle.net/2115/49217 |
Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 高橋 順一
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