Nickel-Promoted Carboxylation/Cyclization Cascade of Allenyl Aldehyde under an Atmosphere of CO2


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Title:	Nickel-Promoted Carboxylation/Cyclization Cascade of Allenyl Aldehyde under an Atmosphere of CO2
Authors:	Takimoto, Masanori Browse this author
	Kawamura, Mitsunobu Browse this author
	Mori, Miwako Browse this author →KAKEN DB
	Sato, Yoshihiro Browse this author →KAKEN DB
Keywords:	allenes
	aldehydes
	carboxylic acid
	cyclization
	nickel
Issue Date:	Jun-2011
Publisher:	Georg Thieme Verlag
Journal Title:	Synlett
Volume:	2011
Issue:	10
Start Page:	1423
End Page:	1426
Publisher DOI:	10.1055/s-0030-1260565
Abstract:	In the presence of a stoichiometric amount of Ni(0) complex, allenyl aldehydes smoothly reacted with carbon dioxide at an ambient temperature and pressure in a regioselective manner. The reaction involves an intramolecular cyclization of aldehyde and allene moieties to afford cyclic carboxylic acid derivatives having a hydroxyl group.
Rights:	© 2011 Georg Thieme Verlag
Type:	article (author version)
URI:	http://hdl.handle.net/2115/49337
Appears in Collections:	薬学研究院 (Faculty of Pharmaceutical Sciences) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 佐藤美洋

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