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Peer-reviewed Journal Articles, etc >
Electrochemical synthesis of methyl-3,5,7-trifluoroadamantane-1-carboxylate under recycling use of ionic liquid media
| Title: | Electrochemical synthesis of methyl-3,5,7-trifluoroadamantane-1-carboxylate under recycling use of ionic liquid media |
| Authors: | Monoi, Miki Browse this author | | Hara, Shoji Browse this author →KAKEN DB |
| Keywords: | Electrochemical fluorination | | Adamantane | | Ionic liquid | | Pyridine-5HF | | Recycle |
| Issue Date: | Aug-2012 |
| Publisher: | Elsevier B.V. |
| Journal Title: | Journal of Fluorine Chemistry |
| Volume: | 140 |
| Start Page: | 28 |
| End Page: | 30 |
| Publisher DOI: | 10.1016/j.jfluchem.2012.04.006 |
| Abstract: | Methyl-3,5,7-trifluoroadamantane-1-carboxylate, a key intermediate for the synthesis of 1-amino-3,5,7-trifluoroadamantane (trifluoroamantadine), was synthesized by the electrochemical fluorination of methyl adamantane-1-caroxylate in pyridine-5HF under constant current conditions. After the reaction, the product was extracted from pyridine-5HF by hexane-CH2Cl2, and recovered pyridine-5HF was used repeatedly. |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/50058 |
| Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 原 正治
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